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Exo- and endo-6-hydroxy- and 6,7-epoxytropanes; Total synthesis of scopine, pseudoscopine, and nor-derivatives

โœ Scribed by David E Justice; John R Malpass


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
286 KB
Volume
36
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Synthesis of exo- a
โœ D. E. JUSTICE; J. R. MALPASS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 2 views

Synthesis of exo-and endo-6,7-Epoxytropanes. -The formation and cyclization of N-protected 2,3-epoxy-4-amino-cycloheptanol derivatives provides a practical route to the title compounds. Whereas the epoxidation of cyclooct-2-enol proceeds with high anti-stereoselectivity as demonstrated in the prece