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ChemInform Abstract: Synthesis of exo- and endo-6,7-Epoxytropanes.

✍ Scribed by D. E. JUSTICE; J. R. MALPASS

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of exo-and endo-6,7-Epoxytropanes.

-The formation and cyclization of N-protected 2,3-epoxy-4-amino-cycloheptanol derivatives provides a practical route to the title compounds. Whereas the epoxidation of cyclooct-2-enol proceeds with high anti-stereoselectivity as demonstrated in the preceding paper, treatment of (I) under similar conditions affords a mixture of (II) and (III). Hydride reductions and hydrogenolysis lead to conversion into compounds with NMe or NH groups. -(JUSTICE, D.

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