Exit in the Emulsion Polymerization of Vinyl Acetate
β Scribed by De Bruyn, Hank; Gilbert, Robert G.; Ballard, Mathew J.
- Book ID
- 121206734
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 123 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0024-9297
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## Abstract It is generally admitted that the SmithβEwart equation is not applicable to the emulsion polymerization of vinyl acetate. This is considered to be due to two factors, namely, (__1__) the great solubility in water of vinyl acetate and (__2__) the fact that vinyl acetate is easily subject
Transport of free radicals out of latex particles into the aqueous phase plays an important role in the emulsion polymerization of vinyl acetate. This so-called "desorption" process involves chain transfer to monomer which generates a mobile an8 rather stable monomer-unit free radical followed by th