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Continuous emulsion polymerization. Modeling oscillations in vinyl acetate polymerization

✍ Scribed by C. Kiparissides; J. F. MacGregor; A. E. Hamielec


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Volume
23
Category
Article
ISSN
0021-8995

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Reaction kinetics of vinyl acetate emuls
✍ Chorng-Shyan Chern; Gary W. Poehlein πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 913 KB

Transport of free radicals out of latex particles into the aqueous phase plays an important role in the emulsion polymerization of vinyl acetate. This so-called "desorption" process involves chain transfer to monomer which generates a mobile an8 rather stable monomer-unit free radical followed by th