## Abstract A new method for the synthesis of tin‐carbon bonds is described. The synthesis involves the non‐catalysed addition of organo‐tin hydrides to olefinic double bonds at moderate temperatures (60–100°). This method allows the preparation of a variety of hitherto unknown types of functionall
Exclusive thiophilic addition of organo-magnesium compounds to a thioketone
✍ Scribed by Patrick Metzner; Jean Vialle; Alain Vibet
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 147 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Grignard reagents such as isopropyl-and tert-butylmagnesium halide (2a: X = Cl; 2b: X = Br) react with tert-butylphosphaacetylene (1) in a regio-and stereoselective 1,2-addition process at -78 °C to give the 2-phospha-1-vinylmagnesium halides 3a,b in high yields. At elevated temperatures, the [ ‡] P