A small but detectable intermolecular spin-spin coupling (J ) is predicted by density functional calculations on van der Waals bonded dimers like methane-benzene and benzene-benzene, as shown in the picture.
β¦ LIBER β¦
Excitonic coupling in van der waals complexes: The anisole dimers
β Scribed by Massimiliano Pasquini; Giangaetano Pietraperzia; Giovanni Piani; Maurizio Becucci
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 374 KB
- Volume
- 993
- Category
- Article
- ISSN
- 0022-2860
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The vibralronal level swucture of the S, --+ S, transtlton of lrans-slilbene-Ar, was inierrogaled by mass-resolved resonance kvtFpholon ionization speclroscopy in supersonic beams. CombinaGon bands provide evidence for inxermode couphng between rhe vibrational excilation of the relative molion of Ar