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Coupling between intramolecular and intermolecular nuclear motion in a large van der waals complex

✍ Scribed by Dar Bahatt; Uzi Even; Joshua Jortner

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 476 KB
Volume: 117
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80296-7

No coin nor oath required. For personal study only.

✦ Synopsis

The vibralronal level swucture of the S, --+ S, transtlton of lrans-slilbene-Ar, was inierrogaled by mass-resolved resonance kvtFpholon ionization speclroscopy in supersonic beams. CombinaGon bands provide evidence for inxermode couphng between rhe vibrational excilation of the relative molion of Ar and trans-rrilbene (TS) m TS Ar and an inlramolerxlar vibration of 7% which is manifesled by the linear dependence of the intermolecular wbralional energy on the vIbrational quanlum number of Ihe innamolecular motion.

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