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Excited States of [3.3](4,4′)Biphenylophane: The Role of Charge-Transfer Excitations in Dimers With π−π Interaction

✍ Scribed by Pabst, Mathias; Köhn, Andreas

Book ID
120322595
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
439 KB
Volume
114
Category
Article
ISSN
1089-5639

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In~mol~~ 2pn\* + 3dn charge transfer in the excited state of phenyl~e occurs very rapidly (<IO ps) both in ?&Fat 293 K and in EPA glass at 77 K. At room temperature a Iong;lived 425 nm transient (which is assgned to a reananged intermediate) is produced with a nse time of 30 ps, showing that the tra