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Excited states in benzalazine photochemistry

✍ Scribed by Marye Anne Fox; Roger W. Binkley


Book ID
104230079
Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
173 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis


During the past several years we have been investigating the photochemistry of bensalazine (1) * These efforts, which to date primarily have been concerned with product identification3 and mechanistic interpretation4, recently have led to a detailed scheme for understanding the photochemical reactions of this compound'. We have now investigated the nature of the excited states C6H5CH=+lN-CHC6H5 hY CH30H


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INDO calculations arc carried OUI on the first few excited states ofmethylcne fluoride. The cffe'ct of the level of configuration interaction on prcdiclcd state ordering, excited state geometries, and cscited state bond energies is discussed.