Excited-state intramolecular proton transfer emission of piroxicam in aqueous β-cyclodextrin solutions
✍ Scribed by Yong Hee Kim; Dae Won Cho; Seong Gwan Kang; Minjoong Yoon; Dongho Kim
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 702 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0022-2313
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Rate constants for the exawd-slate protolyuc rcactmn of F-nophthylanune In alkalrne aqueous solu~ons have been delemuned usmg nanosecond pulse fluoromeuy. and the excited-slate pK has been derived from the rate cons~~~ls It 1s ancludd whet &naphthylamme follows a two-state reversible proton-uansfcr
Emission spectra of pN,Ndimethylamino benzonitrile (DMABN) in aqueous &cyclodextrine @CD) solutions are reported, In ECD two distinct kinds of emission are observed, one with enhanced nonpolar emission (at 355 nm) and the other exhibiting enhanced TICT emission (at 480 nm). The former is attributed
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