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Kinetic study of excited-state proton-transfer reaction in β-naphthylamine

✍ Scribed by J. Shah; H.C. Pant; D.D. Pant; H.C. Pant


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
288 KB
Volume
115
Category
Article
ISSN
0009-2614

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✦ Synopsis


Rate constants for the exawd-slate protolyuc rcactmn of F-nophthylanune In alkalrne aqueous solu~ons have been delemuned usmg nanosecond pulse fluoromeuy. and the excited-slate pK has been derived from the rate cons~~~ls It 1s ancludd whet &naphthylamme follows a two-state reversible proton-uansfcr reactton m 11s elcctromcaliy excwd stale


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Kinetics of excited-state proton transfe
✍ Brian S. Vogt; Stephen G. Schulman 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 364 KB

## 3aminoacridme (I) has been used to extend the quantitation of acited-state proton-transfer kinetics in concentrated acid media to ==13 hl sulfuric acid. The hydration requirement of tire reaction and the reasons for its not attaining equilibrium witbin the lifetime of the excited state are disc