Excited state interaction between 2-N,N-dimethylaminopyridine and p-nitroaniline
โ Scribed by J. Wolleben; A.C. Testa
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 433 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0047-2670
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๐ SIMILAR VOLUMES
The first excited singlet state, an intramofecular charge transfer state, of p-N,N-dimethylaminohenzonitrile (DhWBN) is quenched by tertiary amines. The quenching rate cannot be correlated with the oxidation potential of the amines, but is conrrolled by the size of the amme alkyl group. This unusual
Low-pressure flowing afterglow experiments with Ne carrier gas have been performed to obtam the initial Nz(B) vibrational distributions and the Nz@) formation rate constants for Xe(3P2) and Kr(3P,) excitation-transfer reactions to Nz. The N\*(C) formation rate constant for Ar(3Pz) + N2 also was meas