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Excited-State Deprotonation and H/D Exchange of an Iridium Hydride Complex

✍ Scribed by Tomoyoshi Suenobu; Dirk M. Guldi; Seiji Ogo; Shunichi Fukuzumi


Book ID
101527782
Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
159 KB
Volume
115
Category
Article
ISSN
0044-8249

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An improved bidentate complex of iridium
✍ John M. Herbert; Andrew D. Kohler; Alan H. McNeill πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 French βš– 128 KB πŸ‘ 1 views

Iridium(I) complexes 1, containing bidentate phosphines, and 3, with arsine ligands, are generated in situ. These species mediate hydrogen isotope exchange in a variety of aromatic substrates including benzyl ketones. Although the catalytic activities of complexes 1 and 3 are generally unexceptional