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Electronic and Steric Effects in the Insertion of Alkynes into an Iridium(III) Hydride

โœ Scribed by Li, Xingwei; Vogel, Tiffany; Incarvito, Christopher D.; Crabtree, Robert H.


Book ID
126786428
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
347 KB
Volume
24
Category
Article
ISSN
0276-7333

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## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __transโ€__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, paraโ€toluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy