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Excited State Chemistry of the Ferrocyanide Ion in Aqueous Solution. II. Photoaquation

✍ Scribed by Shirom, Miriam

Book ID
120539859
Publisher
American Institute of Physics
Year
1971
Tongue
English
Weight
580 KB
Volume
55
Category
Article
ISSN
0021-9606

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Luminescence lifetimes of rhodium(III) h
Luminescence lifetimes of rhodium(III) halopentaammines in aqueous solution. Direct comparison of excited state lifetimes with photoaquation quantum yields
✍ Michael A. Bergkamp; Richard J. Watts; Peter C. Ford; James Brannon; Doug Magde πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 367 KB

Luminescence lifetimes and photoaquation quantum yields of RhAsX\* (A = NH3 or ND3, X-= Cl-or Br-) measured in aqueous solution indicate that emission and aquation are competitive processes of the same ligand field excited state. Lifetimes are lo-30 ns with the longer lived perdeuterio complexes als