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Excited-state and ground-state reactivities of para-substituted benzyl radicals toward molecular oxygen

โœ Scribed by Tokumura, Kunihiro; Ozaki, Tomomi; Nosaka, Hideyo; Saigusa, Yoko; Itoh, Michiya


Book ID
127121994
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
903 KB
Volume
113
Category
Article
ISSN
0002-7863

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The diphenyl ketyl radical which is formed upon photolysis of a-phenyl benzoin is produced in its excited state upon intense pulsed laser irradiation. Using the techniques of time-resolved absorption and emission spectroscopy, reaction rate constants for the ground and excited states of this radical