Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu
✦ LIBER ✦
Reactivities of diethylhydroxylamine and thiols towards excited states of alkoxy and alkyl radicals: A comparison
✍ Scribed by M.V. Encina; E.A. Lissi; H. Soto
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 516 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0047-2670
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