The phosphorescence quantum yield ofbenzaldehyde vapour has been measured as a function of excitation energy and pressure (l-300 Torr) of nitrogen as a foreign gas. It is shown that the yield varies greatly as the excitation energy is varied from S0-+S2 to So-&, indicating that benzaldehyde excited
Excitation-energy dependence of phosphorescence quantum yield of benzaldehyde vapour at low pressure
β Scribed by Takao Itoh; Takeshi Takemura; Hiroaki Baba
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 269 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The phosphorescence quantum yield of benzaldehyde vapour was measured at low pressure (down to 2 mtorr) as a function of excitation wavelen$h. The quantum yield is essentially constant in the range of excitation energy corresponding to the S 1 (n, n*) state, but it decreases very rapidty as the excitation energy is raised to the value corresponding to S~(S, a*), indicating that the phosphorescence property of the benzaldehyde molecule varies, depending on the nature of the singlet state to which the molecule is initially excited.
π SIMILAR VOLUMES
Decay of emission from the metal-to-l&and charge transfer (MLCT) excited state of Ru(bpy):+ (bpy=2,2'-bipyridine) was studied by single photon counting as well as by nanosecond time-resolved emission spectroscopy in 4 : 1 ethanol-methanol. While the MLCT emission decay of \*Ru( bpy):+ could bc fitte
The formation of hydrated electrons and H atoms from phenol in neutral aqueous solutions has been studied by cxcitation in its first and second excited singlet state. The quantum yields of both H and c;q show a strong increase at higher cxcitation energies. However, this increase cannot fully eccoun