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Excitation-energy dependence of phosphorescence quantum yield of benzaldehyde vapour at low pressure

✍ Scribed by Takao Itoh; Takeshi Takemura; Hiroaki Baba


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
269 KB
Volume
40
Category
Article
ISSN
0009-2614

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✦ Synopsis


The phosphorescence quantum yield of benzaldehyde vapour was measured at low pressure (down to 2 mtorr) as a function of excitation wavelen$h. The quantum yield is essentially constant in the range of excitation energy corresponding to the S 1 (n, n*) state, but it decreases very rapidty as the excitation energy is raised to the value corresponding to S~(S, a*), indicating that the phosphorescence property of the benzaldehyde molecule varies, depending on the nature of the singlet state to which the molecule is initially excited.


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