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Non-radiative processes of benzaldehyde vapour: excitation energy dependence of the phosphorescence quantum yield in the presence of a foreign gas

✍ Scribed by Takao Itoh


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
368 KB
Volume
133
Category
Article
ISSN
0009-2614

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✦ Synopsis


The phosphorescence quantum yield ofbenzaldehyde vapour has been measured as a function of excitation energy and pressure (l-300 Torr) of nitrogen as a foreign gas. It is shown that the yield varies greatly as the excitation energy is varied from S0-+S2 to So-&, indicating that benzaldehyde excited into S, decays by a non-radiative process which is different from that taken by the molecule excited into S2.