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Exciplex formation between aromatic amines and 4-dimethylamino-2-pyridyl 3-pyridyl ketone

✍ Scribed by Robert G. Brown; Stephen Henderson; Bernadette May; Julie Shankey


Book ID
103493908
Publisher
Elsevier Science
Year
1984
Weight
338 KB
Volume
26
Category
Article
ISSN
0047-2670

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a b s t r a c t Heating a neat 1:2 mixture of 2-picolylamine and 2-cyanopyridine followed by treatment of the resultant red gummy substance with aqueous KOH resulted in the isolation of 2,4,5-tris(2-pyridyl)imidazole (1a) as the major product and N-(3-(2-pyridyl)imidazo[1,5-a]pyridine)picolinamidine