Exchange-transfer in polynuclear mixed-valence clusters with one delocalized electron
✍ Scribed by J.J. Borrás-Almenar; E. Coronado; R. Georges; A.V. Palii; B.S. Tsukerblat
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 725 KB
- Volume
- 220
- Category
- Article
- ISSN
- 0375-9601
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📜 SIMILAR VOLUMES
Possible trapped valence states in trimeric mixed-valence clusters are considered. The adiabatic potential in the space of a doubly-degenerate e vibration is calculated. Conditions under which minima with different electron distributions exist are determined. The coexistence of localized and delocal
The m.ttrI\ elcmcnt for electron tramiier betseen t\ho magnettc tons 1s strongly mfluenccd by exchange coupltng A formula IS glbcn for the tntcnstty of an opttcal mtcrvalencc transItIon m such an e\changexoupled pau as a function of temperaturc. Compounds ha\lng atoms of a metalhc element m differen