𝔖 Bobbio Scriptorium
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Electron delocalization in trinuclear mixed-valence clusters

✍ Scribed by S.A. Borshch; I.N. Kotov; I.B. Bersuker

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
255 KB
Volume
89
Category
Article
ISSN
0009-2614

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✦ Synopsis

Possible trapped valence states in trimeric mixed-valence clusters are considered. The adiabatic potential in the space of a doubly-degenerate e vibration is calculated. Conditions under which minima with different electron distributions exist are determined. The coexistence of localized and delocalized distributions is possible.

πŸ“œ SIMILAR VOLUMES

MO model of electron delocalisation in m
MO model of electron delocalisation in mixed-valence biotahedral clusters
✍ V. Robert; S.A. Borshch; B. Bigot πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 552 KB

A simple extended Hiickel type molecular orbital model is proposed for mixed-valence bioctahedral clusters. The model allows the study of the delocalisation of the excess electron in these systems as a function of the arrangement of octahedral units, metal-metal distances and electronic configuratio