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Exchange reaction of oxiranes with β-hydroxyalkyl sulfides, selenides,-amines, and-phosphines

✍ Scribed by A. D. Malievskii

Book ID
105595892
Publisher
Springer
Year
2000
Tongue
English
Weight
663 KB
Volume
49
Category
Article
ISSN
1573-9171

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Reaction of phenyliodonium ylides of β-d
Reaction of phenyliodonium ylides of β-dicarbonyl compounds with allylic sulfides and selenides
✍ Rui-Yang Yang; Li-Xin Dai; Ru-Jian Ma 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 332 KB

## Abstract An efficient and mild reaction for introducing an allylic moiety and an alkylthio‐ or alkylseleno‐group onto the α‐carbon of β‐dicarbonyl compounds in one step by tandem transylidation and [2,3]‐sigmatropic rearrangement is described.