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Exchange Coupling in Carboxylato-Bridged Dinuclear Copper(II) Compounds: A Density Functional Study

✍ Scribed by Antonio Rodríguez-Fortea; Pere Alemany; Santiago Alvarez; Eliseo Ruiz


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
334 KB
Volume
7
Category
Article
ISSN
0947-6539

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Ferromagnetic Interaction in an Asymmetr
✍ Christophe Aronica; Erwann Jeanneau; Hani El Moll; Dominique Luneau; Béatrice Gi 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 243 KB 👁 2 views

## Abstract A new end‐to‐end azido double‐bridged copper(II) complex [Cu~2~L~2~(N~3~)~2~] (1) was synthesized and characterized (L=1,1,1‐trifluoro‐7‐(dimethylamino)‐4‐methyl‐5‐aza‐3‐hepten‐2‐onato). Despite the rather long CuCu distance (5.105(1) Å), the magnetic interaction is ferromagnetic with