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A Theoretical Study of the Exchange Coupling in Hydroxo- and Alkoxo-Bridged Dinuclear Oxovanadium(IV) Compounds

✍ Scribed by Antonio Rodríguez-Fortea; Pere Alemany; Santiago Alvarez; Eliseo Ruiz


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
216 KB
Volume
2004
Category
Article
ISSN
1434-1948

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A Theoretical Study of the Nearest Cu···
✍ Yi-Quan Zhang; Cheng-Lin Luo 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 160 KB

## Abstract A density functional study of the exchange coupling interactions between the two nearest Cu^II^ centers in [LaCu~6~] and [YCu~6~] is presented. Two approaches show that the Cu···Cu antiferromagnetic interactions increase with a decrease of the ionic radius of the diamagnetic central La^