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Excess partial molar volumes of {xCH3(CH2)3O(CH2)2OH+(1-xH2O} in the water-rich region

✍ Scribed by Yoshikata Koga; Jesper Kristiansen; Aase Hvidt

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 175 KB
Volume: 25
Category: Article
ISSN: 0021-9614
DOI: 10.1006/jcht.1993.1006

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✍ Amalendu Pal; Yoginder P. Singh 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 394 KB

The excess molar volumes V E m of [xH(CH2)n {O(CH2)2}3OH+(1-x)H2O] for n=1, 2, and 4 have been measured using a continuous-dilution dilatometer over the whole mole-fraction range at the temperature 298.15 K. All three mixtures show negative V E m . The results were used to estimate the apparent mola

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✍ A. Pal; W. Singh 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 268 KB

The excess molar volumes V E m of {xCH3(CH2)3OH + (1x)H( CH2)n(OCH2CH2)3OH} for n = 1, 2, and 4 were determined as a function of mole fraction x using a continuous-dilution dilatometer at the temperature 298.15 K. The V E m values decreased as the alkyl chain length of the alkoxyethanol increased. E

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Excess molar volumes at the temperature 298.15 K were measured for , and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate