Excess molar volumes V E m have been calculated from measured density values over the whole composition range at T = 298.15 K and atmospheric pressure for six {N -methyl-2-pyrrolidinone + 1,1-dimethylethyl methyl ether, or dipropyl ether, or 1,1-dimethylpropyl methyl ether, or diisopropyl ether, or
Excess molar enthalpies of the ternary mixtures: Methyl tert-butyl ether (or di-isopropyl ether) + n-octane + 2-methylpentane at 293.15 K
β Scribed by Zhaohui Wang; Christopher Q. Lan
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 300 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0008-4034
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π SIMILAR VOLUMES
Measurements of excess molar enthalpies at the temperature 298.15 K in a flow microcalorimeter, are reported for the ternary mixtures where Ξ½ = 5 and 6. Smooth representations of the results are described and used to construct constant-enthalpy contours on Roozeboom diagrams. It is shown that usefu
The results were compared with the values of H E m for the related mixtures, and the possible hydrogen bonding between the alkyne and the ether noted. Various theories of liquid mixtures were fitted with the results. The H E m results were discussed in terms of the NRTL and UNIQUAC models, and were
Flow-microcalorimetric measurements of excess molar enthalpies H E m at the temperatures 298.15 K and 308.15 K are reported for 4x(CH3)3CCH2CH(CH3)2, or CH3(CH2)4CH.CH2, or CH3(CH2)3CH.CH2, or C6H5CH3 + (1 -x)CH3OC(CH3)35 and 4xCH3(CH2)4CH.CH2, or CH3(CH2)3CH.CH2, or C6H5CH3 + (1 -x)CH3OC(CH3)2C2H55
We report liquid-liquid equilibrium data for the ternary system {x1tert-butyl methyl ether(C5H12O)+x2water+(1-x1-x2)1-octanol} at 298.15 and 308.15 K. The data were satisfactorily fitted with UNIQUAC and NRTL equations, and were satisfactorily predicted by the UNIFAC group contribution method.
Flow-microcalorimetric measurements of excess molar enthalpies H E m at the temperature 298.15 K are reported for [x{CH 3 (CH 2 ) 4 CH 3 , or CH 3 (CH 2 ) 6 CH 3 , or CH 3 (CH 2 ) 8 CH 3 , or CH 3 (CH 2 ) 10 CH 3 , or CH 3 (CH 2 ) 14 CH 3 , or c-C 6 C 12 , or CH 3 (CH 2 ) 4 CH CH 2 , or CH 3 (CH 2 )