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Excess molar enthalpies of (hexane, or octane, or decane, or dodecane, or hexadecane, or cyclohexane, or 1-heptene, or 1-heptyne, or 2,2,4-trimethylpentane  +  ethyl 1,1-dimethylpropyl ether) at the temperature 298.15 K

✍ Scribed by T.M. Letcher; U. Domańska

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
135 KB
Volume
31
Category
Article
ISSN
0021-9614

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✦ Synopsis

Flow-microcalorimetric measurements of excess molar enthalpies H E m at the temperature 298.15 K are reported for [x{CH 3 (CH 2 ) 4 CH 3 , or CH 3 (CH 2 ) 6 CH 3 , or CH 3 (CH 2 ) 8 CH 3 , or CH 3 (CH 2 ) 10 CH 3 , or CH 3 (CH 2 ) 14 CH 3 , or c-C 6 C 12 , or CH 3 (CH 2 ) 4 CH CH 2 , or CH 3 (CH 2 ) 4 C CH, or

in order to investigate the interaction between a straight chain hydrocarbon and ethyl 1,1-dimethylpropyl ether. Over the whole composition range all the mixtures, with the exception of (1-heptene or 1-heptyne + ether), are endothermic. The experimental values are correlated by means of UNIQUAC and NRTL models.

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