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Excess molar enthalpies of some examples of (a dichloroalkane+a ket-2-one) at the temperature 298.15 K

✍ Scribed by E.R. López; J. Garcı́a; J. Fernández; M.I.Paz Andrade


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
135 KB
Volume
25
Category
Article
ISSN
0021-9614

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The excess molar enthalpies H E m [x{BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl} + (1x)(CCl4 or C6H6)] have been measured at the temperature 298.15 K. Mixing was endothermic at all mole fractions except for [x{BrCH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl} + (1x)C6H6]. The so-called '

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The excess enthalpies H E m of [x {BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl}+(1x){CH3(CH2)5CH3 or CH3(CH2)14CH3 or c-(CH2)6} have been measured at the temperature 298.15 K. Mixing was endothermic at all x and the H E m s were found to vary in the sequence: BrCH2CH2Cl q BrCH2Cl q Br

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✍ U Domańska; J Łachwa; T.M Letcher 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 109 KB

Excess molar volumes V E m have been calculated from measured density values over the whole composition range at T = 298.15 K and atmospheric pressure for six {N -methyl-2-pyrrolidinone + 1,1-dimethylethyl methyl ether, or dipropyl ether, or 1,1-dimethylpropyl methyl ether, or diisopropyl ether, or