## Ž . Ž . 4 x c-CH O q 1 y x y x c-C H . The experimental data were described through a 2 24 1 2 6 1 2 Redlich᎐Kister type equation. The ternary mixtures exhibit large positive deviations for both properties investigated. Ternary H E and C E data were poorly predicted by rules which m p, m empiri
Excess molar enthalpies of some examples of (a dichloroalkane+a ket-2-one) at the temperature 298.15 K
✍ Scribed by E.R. López; J. Garcı́a; J. Fernández; M.I.Paz Andrade
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 135 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Excess molar enthalpies and excess molar heat capacities at T = 298.15 K were determined for {xCHCl3 Both experimental properties were represented by a Redlich-Kister type equation. The large negative values of the excess enthalpies and the positive values of the excess heat capacities observed in
The excess molar enthalpies H E m [x{BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl} + (1x)(CCl4 or C6H6)] have been measured at the temperature 298.15 K. Mixing was endothermic at all mole fractions except for [x{BrCH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl} + (1x)C6H6]. The so-called '
The excess enthalpies H E m of [x {BrCH2Cl or BrCH2CH2Cl or BrCH2CH2CH2Cl or BrCH2(CH2)2CH2Cl}+(1x){CH3(CH2)5CH3 or CH3(CH2)14CH3 or c-(CH2)6} have been measured at the temperature 298.15 K. Mixing was endothermic at all x and the H E m s were found to vary in the sequence: BrCH2CH2Cl q BrCH2Cl q Br
Excess molar volumes V E m have been calculated from measured density values over the whole composition range at T = 298.15 K and atmospheric pressure for six {N -methyl-2-pyrrolidinone + 1,1-dimethylethyl methyl ether, or dipropyl ether, or 1,1-dimethylpropyl methyl ether, or diisopropyl ether, or