Excess molar volumes of (butan-1-ol, or butan-2-ol, or 2-methylpropan-1-ol, or 2-methylpropan-2-ol + benzene, or toluene) over the entire range of composition have been measured dilatometrically at the temperature 308.15 K. The results indicate that the branching of an alkyl group of butanol near th
Excess molar enthalpies of mixing of (2-butanol + benzene, or toluene, or o-, or m-, or p-xylene) at the temperature 308.15 K
β Scribed by Umesh Bhardwaj; K.C. Singh; Sanjeev Maken
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 121 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0021-9614
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β¦ Synopsis
Excess molar enthalpies H E m of (2-butanol + benzene, or toluene, or o-, or m-, or p-xylene) over the entire composition range at the temperature 308.15 K have been measured in a flow microcalorimeter. The results are analysed in terms of a Mecke-Kempter type association model with a Flory contribution term and a quasi-lattice model by Barker.
π SIMILAR VOLUMES
Excess molar enthalpies of 2-methylpropan-2-ol q benzene, or toluene, or o-, or m-, or . p-xylene have been measured in a flow microcalorimeter over the entire composition range at the temperature 308.15 K . The results are analysed in terms of the MeckeαKempter type association model with a Flory c
The excess molar Gibbs energies of mixing for 2-methylpropan-2-ol q benzene, or toluene, . or o-, or m-, or p-xylene at T s 308.15 K have been calculated by the Barker method from vapour pressure data measured by the static method. The Gibbs energies of mixing for these binary systems are also analy
Excess molar volumes V E m and excess molar heat capacities C E p,m were determined for mixtures of benzonitrile with chlorobenzene, or benzene, or toluene at the temperatures 298.15 K and 303.15 K. For all the systems the values of V E m were negative over the whole range of compositions and values
Excess molar enthalpies of (2-butanone + cyclohexane, or methylcyclohexane, or toluene, or chlorobenzene, or cyclohexanone) and excess molar heat capacities of (2-butanone + benzene, or toluene, or chlorobenzene, or cyclohexanone) were measured at T = 298.15 K. Aliphatic systems were endothermic and