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Excess molar enthalpies of mixing of (2-butanol + benzene, or toluene, or o-, or m-, or p-xylene) at the temperature 308.15 K

✍ Scribed by Umesh Bhardwaj; K.C. Singh; Sanjeev Maken


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
121 KB
Volume
31
Category
Article
ISSN
0021-9614

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✦ Synopsis


Excess molar enthalpies H E m of (2-butanol + benzene, or toluene, or o-, or m-, or p-xylene) over the entire composition range at the temperature 308.15 K have been measured in a flow microcalorimeter. The results are analysed in terms of a Mecke-Kempter type association model with a Flory contribution term and a quasi-lattice model by Barker.


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Excess molar enthalpies of (2-butanone + cyclohexane, or methylcyclohexane, or toluene, or chlorobenzene, or cyclohexanone) and excess molar heat capacities of (2-butanone + benzene, or toluene, or chlorobenzene, or cyclohexanone) were measured at T = 298.15 K. Aliphatic systems were endothermic and