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Excess Electron Transfer in DNA Studied by Pulse Radiolysis and γ-Radiolysis of Naphthalimide and Iodouridine Modified ODN

✍ Scribed by Kawai, Kiyohiko; Kimura, Takumi; Kawabata, Kazuhiro; Tojo, Sachiko; Majima, Tetsuro


Book ID
127083126
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
111 KB
Volume
107
Category
Article
ISSN
0022-3654

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One-electron oxidation and demetalation
✍ Haim Levanon; P. Neta 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 356 KB

Formation of cation radicals by pulse radiolysis of metalloporphyrins and chlorophyll a in 1,2dichIoroethane is reported. Demetalation of the metalloporphyrin by radiolytically produced HCl is also observed. Rate constants for demetalation of ZnTPP and Chl a are 1 .I X IO8 and = 3 X IO8 h!-' s-I\_ O