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Intramolecular electron transfer and SN2 reactions in the radical anions of 1-(4-biphenylyl)-.omega.-haloalkane studied by pulse radiolysis

โœ Scribed by Kigawa, Hitoshi; Takamuku, Setsuo; Toki, Susumu; Kimura, Norio; Takeda, Seishi; Tsumori, Kunihiko; Sakurai, Hiroshi; Sakurai, Hiroshi


Book ID
126057819
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
513 KB
Volume
103
Category
Article
ISSN
0002-7863

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Formation of semiquinone radical in the
โœ Ravi Joshi; Tapan K. Ghanty; Tulsi Mukherjee ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 638 KB

Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics