𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Example of Highly Stereoregulated Ruthenium Amidine Complex Formation: Synthesis, Crystal Structures, and Spectral and Redox Properties of the Complexes [Ru II (trpy){NC 5 H 4 CHNN(C 6 H 5 )C(CH 3 )NH}](ClO 4 ) 2 ( 1 ) and [Ru II (trpy)(NC 5 H 4 CHNNHC 6 H 5 )Cl]ClO 4 ( 2 ) (trpy = 2,2‘:6‘,2‘ ‘-Terpyridine)

✍ Scribed by Mondal, Biplab; Puranik, Vedavati G.; Lahiri, Goutam Kumar

Book ID
126445336
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
143 KB
Volume
41
Category
Article
ISSN
0020-1669

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Diruthenium Complexes [{(acac) 2 Ru III
Diruthenium Complexes [{(acac) 2 Ru III } 2 (μ-OC 2 H 5 ) 2 ], [{(acac) 2 Ru III } 2 (μ-L)](ClO 4 ) 2 , and [{(bpy) 2 Ru II } 2 (μ-L)](ClO 4 ) 4 [L = (NC 5 H 4 ) 2 −N−C 6 H 4 −N−(NC 5 H 4 ) 2 , acac = Acetylacetonate, and bpy = 2,2‘-Bipyridine]. Synthesis, Structure, Magnetic, Spectral, and Photophysical Aspects
✍ Kar, Sanjib; Chanda, Nripen; Mobin, Shaikh M.; Datta, Anindya; Urbanos, Francisc 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 193 KB
Synthesis, Structural Characterisation a
Synthesis, Structural Characterisation and Reactivity of New Dinuclear Monocyclopentadienyl Imidoniobium and -tantalum Complexes − X-ray Crystal Structures of [{Nb(η5-C5H4SiMe3)Cl2}2(μ-1,4-NC6H4N)], [{Ta(η5-C5Me5)Cl2}2(μ-1,4-NC6H4N)] and [{Ta(η5-C5Me5)(CH2SiMe3)2}2(μ-1,4-NC6H4N)]
✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3