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Synthesis of 5-ansa-zirconocene complexes and crystal structure of [Zr{C6H4(CH2C5H4)2-1,3}Cl2]

✍ Scribed by Qian, Changtao; Guo, Jianhua; Ye, Changqing; Sun, Jie; Zheng, Peiju


Book ID
115442849
Publisher
The Royal Society of Chemistry
Year
1993
Tongue
English
Weight
731 KB
Volume
22
Category
Article
ISSN
1472-7773

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## CeH5CHzCsH4)2GdCl.THF]2 (1) and ( C ~H ~C H Z C ~H ~) ~E ~C I . T H F (2) were prepared by the reaction of LnC13 ( Ln=Gd, Er) with benzylcyclopentadienyl sodium in THF and characterized by elemental analysis, IR, 'H NMR, 13C NMR, MS and thermal gravimetry. The crystal structures of both compoun