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Examination of Models for Carbocationic Polymerization: Influence of Chain Length on Carbocation Reactivities

โœ Scribed by Mayr, Herbert; Roth, Michael; Faust, Rudolf


Book ID
120379023
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
207 KB
Volume
29
Category
Article
ISSN
0024-9297

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It is shown that the (established) method of deriving chain-length distributions from propagation probabilities is not fully consistent with the Poissonian character of chain propagation if termination is chain-length dependent: the fluctuation of chain propagation leads to somewhat lower radical co