Exact collinear calculations of the N2 O(X1∑+) → N2(1∑+g) + O(1S) photodissociation process
✍ Scribed by M. Shapiro
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 716 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0009-2614
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## Abstract The title reaction, which is spin‐forbidden for N~2~(X^1^∑) + NO(X^2^Π) production, has been studied from 960 to 1130 K in a high‐temperature photochemistry reactor. No reaction could be observed, indicating __k__ < 1 × 10^−15^ cm^3^ molecule^−1^ s^−1^. It is concluded that there is no
Vacuum oltraviolet photclysis of N20 isolated in ir,-matrices at 4 K gives direct luminescent evidence for the pkotodissocktive piodbction of both O("S) and X(\*D). The matrix icsults zrc compared to reiative atomic quantum yields meas!xed in the gels phase.
Previous work by Manaa and Yarkony has characterized the doublet-quartet crossing region for the title reaction. In the present work, the minimum energy pathways for addition of CH(%) to Nz on the doublet surface and for dissociation of HCNN to HCN+N(S) on the quartet surface are characterized using