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Evidence suggesting the occurrence of [2+3] cycloaddition products in the ion/molecule reactions of suitably substituted allyl cations and olefins

โœ Scribed by M. W. E. M. van Tilborg; R. van Doorn; N. M. M. Nibbering


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
439 KB
Volume
15
Category
Article
ISSN
1076-5174

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The 2ฯ€ + 2ฯ€ cycloaddition of an allyl ca
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Treatment of (lZ,3E)-cycloalkadienes with 2-vinyl-1,3-dioxolane under acidic conditions produced 1:l cycloadducts in which an intermediate ally1 cation added to the dienes to give tram-fused cyclobutanes as the major products.