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Evidence for a [2+4] cycloaddition in the ion-molecule reaction of ionized 1,3-butadiene with vinyl ethyl (methyl) ether in the gas phase

✍ Scribed by R. Van Doorn; N. M. M. Nibbering; A. J. V. Ferrer-Correia; K. R. Jennings


Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
445 KB
Volume
13
Category
Article
ISSN
1076-5174

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Gas-phase polar [4+ + 2] cycloaddition w
✍ Eduardo C. Meurer; Regina Sparrapan; Marcos N. Eberlin 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 135 KB 👁 1 views

## Abstract The intrinsic reactivity of eight gaseous, mass‐selected 2‐azabutadienyl cations toward polar [4^+^ + 2] cycloaddition with ethyl vinyl ether has been investigated by pentaquadrupole mass spectrometric experiments. Cycloaddition occurs readily for all the ions and, with the only excepti