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Evidence on the nature of cobalt-mediated aryl radical cyclisations

โœ Scribed by Andrew J. Clark; Keith Jones

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
209 KB
Volume
30
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Regiochemical

and stereochemical evidence is presented which indicates that cobalt-mediated aryl radical cyclisations involve simple free radicals.

Radical cyclisatton reactions have achieved considerable importance in synthetic chemistry'.

๐Ÿ“œ SIMILAR VOLUMES

Cobalt-mediated aryl radical cyclisation
Cobalt-mediated aryl radical cyclisations: A formal synthesis of physovenine
โœ Andrew J. Clark; Keith Jones ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 567 KB

Abstmct: A synthesis of the te&ahydrofuro[2,3-blindole (3) in 6 step from 4-methoxyaniline involving a key cobalt-mediated aryl radical cycliin is presented. This hetuucycle is a known, late intermediate. in the synthesis of the alkaloid physovenine (2).

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