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Evidence of Fluoride Transfer from the Anion of [Zr{C5H3[SiMe2(η1-NtBu)]2}]+[RB(C6F5)3]− Complexes to the Zirconocenium Cation

✍ Scribed by Jesús Cano; María Sudupe; Pascual Royo; Marta E. G. Mosquera


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
112 KB
Volume
118
Category
Article
ISSN
0044-8249

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Lewis Adducts of the Side-On End-On Dini
✍ Felix Studt; Bruce A. MacKay; Samuel A. Johnson; Brian O. Patrick; Michael D. Fr 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 334 KB

## Abstract Reaction of the side‐on end‐on dinitrogen complex [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐N~2~)] (1; in which NPN=(PhNSiMe~2~CH~2~)~2~PPh), with the Lewis acids XR~3~ results in the adducts [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐NNXR~3~)], XR~3~=GaMe~3~ (2), AlMe~3~ (3), and B(C~6~F~5~)~3~ (4). Th