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Evidence of a previous protonation reaction in the electroreduction of isonicotinamide in basic media

✍ Scribed by R. Marín Galvín; J.M. Rodríguez Mellado


Book ID
103064135
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
267 KB
Volume
34
Category
Article
ISSN
0013-4686

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A note on the mechanism of electroreduct
✍ José Miguel Rodríguez Mellado; Rafael Marín Galvín 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 162 KB

Ahstraet-The electroreduction of isoniazid was studied at pH < 6. On the basis of polarographic and voltammetric measurements and by regarding the Tafel slopes and reaction orders, it was concluded that in a very strongly acidic medium the rate-determining step of the process is the loss of an ammon