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Evidence for the Formation of Singly Bonded Dimers During the Reductive Electrochemistry of Methanofullerenes.

✍ Scribed by Maitena Ocafrain; M. Angeles Herranz; Lucien Marx; Carlo Thilgen; Francois Diederich; Luis Echegoyen

Publisher
John Wiley and Sons
Year
2004
Weight
68 KB
Volume
35
Category
Article
ISSN
0931-7597

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One of the most general catalyst systems, in terms of their efficacy in CÀC, CÀN, and CÀO bond-forming reactions, are those based on the bulky, electron-rich monophosphinobiaryl ligands (Scheme 1). [1] First introduced in 1998, the Pd 0 catalyst based on 1 a demonstrated exceptionally high activity,