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Evidence for the Formation of Singly Bonded Dimers During the Reductive Electrochemistry of Methanofullerenes

✍ Scribed by Maïténa Oçafrain; M. Ángeles Herranz; Lucien Marx; Carlo Thilgen; François Diederich; Luis Echegoyen

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
220 KB
Volume
9
Category
Article
ISSN
0947-6539

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One of the most general catalyst systems, in terms of their efficacy in CÀC, CÀN, and CÀO bond-forming reactions, are those based on the bulky, electron-rich monophosphinobiaryl ligands (Scheme 1). [1] First introduced in 1998, the Pd 0 catalyst based on 1 a demonstrated exceptionally high activity,