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Evidence for surface Ag+ complexes as the SERS-active sites on Ag electrodes

โœ Scribed by T. Watanabe; O. Kawanami; K. Honda; B. Pettinger

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
629 KB
Volume
102
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Evidence is given that SERS-active sites at Ag electrodes are associated with Ag+ ions, forming sparingly soluble surface complc~cs with ligands such as pyridinc molcculcs and halide ions. Such surface A$ coniplcses contribute a factor of >800 to the overall (107-fold) enhancenient, possibly via a resonance Raman effect.

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