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Competition among adsorbed species for surface sites on Ag electrodes as determined by Sers

โœ Scribed by J.F. Owen; T.T. Chen; R.K. Chang; B.L. Laube


Publisher
Elsevier Science
Year
1983
Weight
41 KB
Volume
125
Category
Article
ISSN
0167-2584

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Evidence for surface Ag+ complexes as th
โœ T. Watanabe; O. Kawanami; K. Honda; B. Pettinger ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 629 KB

Evidence is given that SERS-active sites at Ag electrodes are associated with Ag+ ions, forming sparingly soluble surface complc~cs with ligands such as pyridinc molcculcs and halide ions. Such surface A$ coniplcses contribute a factor of >800 to the overall (107-fold) enhancenient, possibly via a r