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Evidence for proton tunneling in the strong base catalyzed elimination reaction of .beta.-phenylethyl substrates

โœ Scribed by Kwart, Harold; Wilk, Kazimiera A.


Book ID
126417717
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
488 KB
Volume
50
Category
Article
ISSN
0022-3263

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The reaction of cyclopropanes like 2,3,4-triphenyl-endo-tricyclo[3.2.1.02'0]octane (la) with base is initiated by proton and not by ele$trov transfer. The facile disrotatory cyclopropyl anion ring opening reaction of 2JR2=CN, M =Ll ) at -75ยฐC does not occur synchronously. 2,3,4-Triphenyl-endo-tricyc