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Evidence for proton tunneling in strong base promoted (stepwise) .beta.-elimination reactions

โœ Scribed by Kwart, Harold; Horgan, Ann G.


Book ID
125953067
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
425 KB
Volume
47
Category
Article
ISSN
0022-3263

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The reaction of cyclopropanes like 2,3,4-triphenyl-endo-tricyclo[3.2.1.02'0]octane (la) with base is initiated by proton and not by ele$trov transfer. The facile disrotatory cyclopropyl anion ring opening reaction of 2JR2=CN, M =Ll ) at -75ยฐC does not occur synchronously. 2,3,4-Triphenyl-endo-tricyc