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Evidence for p-f mixing in U3P4 and U3As4 from optical spectroscopy

✍ Scribed by J. Schoenes; M. Küng; R. Hauert; Z. Henkie

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
471 KB
Volume
47
Category
Article
ISSN
0038-1098

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X-ray photoelectron spectrum of U(4f) in
X-ray photoelectron spectrum of U(4f) in condensates from UF4 and ion bombarded UF4; spectrum of UF3
✍ W.-Y. Howng; R.J. Thorn 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 359 KB

The 4f,, orbital electrons in condensates and ion bombarded powders of IJFa have been inves@sted aith XPS. In both uses the intensity at 382 eV decreases and that at 379 eV increnses. The intensities of the 5f electrons are ronstant. The peak at 379 eV is assigned to UF3.