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Evidence for hydrogen atom abstraction by methyl radicals in the solid state at 77.deg.K

โœ Scribed by Williams, Ffrancon; Sprague, Estel D.

Book ID
126422515
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
269 KB
Volume
93
Category
Article
ISSN
0002-7863

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Hydrogen atom abstraction by methyl radi
Hydrogen atom abstraction by methyl radicals in methanol glasses at 15โ€“100 K: evidence for a limiting rate constant below 40 K by quantum-mechanical tunneling
โœ Reggie L. Hudson; Masaru Shiotani; Ffrancon Williams ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 378 KB

Rate constants for hydrogen atom abstraction by methyl radicals in methanol glasses have been measured from 100 to 15 K. The Arrhenius plot is nonlinear and the reaction rate constant appears to reach a limiting value below 40 K. The r+ suits are discussed in terms of simple models for quantum-mecha