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Deuterium isotope effect on hydrogen atom abstraction by methyl radicals in acetonitrile at 77 K. Evidence for tunneling

โœ Scribed by Sprague, Estel D.

Book ID
120483961
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
750 KB
Volume
81
Category
Article
ISSN
0022-3654

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Hydrogen atom abstraction by methyl radi
Hydrogen atom abstraction by methyl radicals in methanol glasses at 15โ€“100 K: evidence for a limiting rate constant below 40 K by quantum-mechanical tunneling
โœ Reggie L. Hudson; Masaru Shiotani; Ffrancon Williams ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 378 KB

Rate constants for hydrogen atom abstraction by methyl radicals in methanol glasses have been measured from 100 to 15 K. The Arrhenius plot is nonlinear and the reaction rate constant appears to reach a limiting value below 40 K. The r+ suits are discussed in terms of simple models for quantum-mecha